Dorf Ketal Tyzor Organic Titanates, Catalysts and Additives

Selection and quotation of Dorf Ketal materials: Tyzor titanates and zirconates, ACtivate, Unilink and Clearlink catalysts, adsorbents, PX additive components and Insoform PVF.

Tyzor Organic Titanates and Zirconates

Tyzor are organic titanium and zirconium compounds that work as esterification and transesterification catalysts, crosslinkers, surface modifiers and adhesion promoters. Dorf Ketal offers more than 40 Tyzor grades: alkoxy titanates, titanium chelates and alkoxy zirconates.

  • Tyzor TPT: tetra-isopropyl titanate
  • Tyzor TnBT: tetra-n-butyl titanate
  • Tyzor NPZ: tetra-n-propyl zirconate
  • Tyzor AA-65, AA-75 and AA-105 titanium chelates

ACtivate and Tyzor PET and Polyolefin Catalysts

ACtivate are hydrolytically stable titanate catalysts for antimony-free PET bottle and film resins. Grades 420 and 422 serve PET, while grade 428 replaces organotin in polyester can coatings. Tyzor NPT is used with TPT and TnBT in Ziegler-Natta polyolefin production.

  • ACtivate 420 and 422: PET bottle and film resins
  • ACtivate 428: polyester can coatings
  • Tyzor NPT: stereospecific polyolefins
  • ACtivate PET: lower diethylene glycol content

Catalysts and Adsorbents for Feedstock Treatment

Dorf Ketal catalysts and adsorbents serve feedstock treatment in syngas and catalytic reforming processes and hydrogenation and dehydrogenation in the fine chemicals industry. A special grade removes organic sulfur compounds from the liquid phase in hydrotreating.

  • Ammonia cracking catalysts
  • Arsine removal and selective hydrogenation
  • Sulfur and chloride or halide removal
  • Desiccation and catalyst bed support

PX Lubricant and Grease Additive Components

The PX series covers additive components for engine, gear, hydraulic, turbine and compressor oils and greases: anti-wear and extreme pressure additives, friction modifiers, antioxidants, dispersants, antifoamants, metal deactivators and rust inhibitors.

  • PX 3841: non-silicone antifoamant
  • PX 3239: tolutriazole based metal deactivator
  • PX 4005: ashless 1000 MW PIBSI dispersant
  • PX 3806: high-temperature antioxidant

Insoform and Insothane Wire Enamel Materials

Insoform is polyvinyl formal for magnet wire enamels: combined with phenolic resins it gives coatings with high adhesion, thermal stability and mechanical strength, supporting coil life of up to 40 years. Insothane is a blocked poly-isocyanate for solderable wire enamels and varnishes.

  • Insoform: primary magnet wire enamel coatings
  • Insoform: magnetic tape binders and adhesives
  • Insothane CT: solderable polyurethane enamel
  • Transformer coil life of up to 40 years

Coating Chemicals for Electrical Steel

Coating chemicals for fully processed electrical steel in C-3, C-5 and C-6 classes, engineered for various coating systems and line speeds. The range addresses high line speeds, reduced coating thickness and the transition to eco-friendly materials compliant with European RoHS.

  • Coating classes C-3, C-5 and C-6
  • Formulations for various line speeds
  • Compliant with European RoHS
  • Reduced coating thickness

Xylenols and Meta Cresol

Dorf Ketal produces 3,5 Xylenol (3,5 Dimethylphenol, Meta Xylenol) by an in-house catalytic process; the plant was commissioned in 2008. Pharma Grade material is exported to Europe. The range also includes Resin Grade Mixed Xylenol, 2,5 Xylenol and Meta Cresol.

  • 3,5 Xylenol in Pharma Grade
  • Resin Grade Mixed Xylenol
  • 2,5 Xylenol and Meta Cresol
  • Xylenol plant commissioned in 2008

Choosing a Titanate by System and Moisture Sensitivity

Tyzor TPT, TOT and 9000 alkoxy titanates are reactive to moisture and have low to no impact on colour, so they suit silicone RTV-1 sealants, solvent-based acrylics and epoxy adhesives.

Tyzor AA-65, AA-75, AA-105 and IBAY chelates are moisture resistant with a moderate cure rate and moderate colour impact. Tyzor TE is stable in water-based acrylics and polysulfide sealants, and the product guide lists TPT and NBZ with a fast cure for natural rubber.

Cure Profile for Polyurethane and Polyurea

The zirconium-based Unilink 1000 series gives a fast cure profile similar to tin and works with aliphatic and aromatic isocyanates and all polyols; Unilink 1030 suits colour-critical formulations.

The titanium-based Unilink 2000 series gives a slower, delayed cure with a snap final cure similar to mercury, is moisture tolerant and stable in polyols.

Unilink 4100, 4200 and 4230 cure TDI and MDI coating compounds at ambient temperature, and Clearlink 1080 has slower reactivity than Clearlink 1000.

Choosing a PET Polycondensation Catalyst

Compared with antimony catalysts, ACtivate gives higher esterification and polymerization rates, lower diethylene glycol, oligomer and acetaldehyde levels and less haze.

The different crystallinity of the resin shortens mold cycle times for carbonated soft drink bottles and supports light-weighting of hot fill bottles. For polyolefins, titanium alkoxide compounds combined with metal organics serve as Ziegler-Natta catalyst components.

Choosing an Additive Component by Oil Type

PX 3239, a tolutriazole based metal deactivator, is intended for turbine, compressor and hydraulic oils at a dosage of 0.02–0.05 in the manufacturer table. PX 3862, a tolyltriazole and succinic anhydride blend, passivates copper in automotive and industrial gear oils at 0.1–0.5.

The non-silicone antifoamant PX 3841 is dosed at 0.05–0.30 in engine and gear oils, and the PX 3807 antioxidant serves turbine, compressor and aviation oils.

Industrial equipment

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